(Phys.org) —In extreme cold, carbon dioxide huddles near charged oxygen atom outcroppings on the surface of oft-studied titanium dioxide; the carbon dioxide lacks the energy to reach a more protected spot, according to scientists at Pacific Northwest National Laboratory. When heated, the carbon dioxide slides into a more substantial, reactive oxygen vacancy, holes left by missing oxygen atoms. The team tracked the carbon dioxide with a scanning tunneling microscope tip that provided atomic-resolution images.
Tag Archives: Pacific Northwest National Laboratory
Scientists show how cracks propagate through thick and thin layers of frozen liquid water
Whether gas trapped under a frozen water layer flows through cracks or bursts out depends on the layer’s depth and temperature, according to scientists at Pacific Northwest National Laboratory. The water isn’t crystalline ice; it is amorphous solid water, which is disordered and often described as a “frozen” liquid. The team proved that in some cases, gases trapped under amorphous water films are released via fissures that form during crystallization. For thicker trapped gas layers, the gas can escape abruptly before crystallization. This work graced a cover of The Journal of Chemical Physics.
Cybernetic model developed to predict Shewanella metabolic behavior
To further the quest to harness microbes for beneficial uses, scientists from Pacific Northwest National Laboratory and Purdue University developed a promising computational tool for analyzing microbial flux distribution and metabolic engineering. They used the Lumped Hybrid Cybernetic Model (L-HCM), developed by Purdue researchers Dr. Hyun-Seob Song and Dr. Doraiswami Ramkrishna, to predict and simulate the metabolic dynamics of Shewanella oneidensis MR-1 during aerobic growth in a bioreactor.
Making the case for regional modeling: Tackling global environmental issues means adopting smaller, regional approach
(Phys.org) —While it is important to understand how the Earth system works from a process-level basis, it is clear that human activities are increasingly challenging assumptions about how that system works. Factor in climate change, and it is quickly apparent: one size certainly does not fit all. In their paper, “The Regional Nature of Global Challenges: A Need and Strategy for Integrated Regional Modeling,” authors Dr. Kathy Hibbard and Dr. Anthony Janetos of Pacific Northwest National Laboratory make the case for integrated regional-scale analyses, where they discuss how regional dynamic interactions between human and natural systems provide insight into mitigation and adaptation strategies, their tradeoffs and consequences, and how these influence the global Earth system. …read more
Source: FULL ARTICLE at Phys.org
Unique calibration technique uncovers details of precipitation in a climate model
(Phys.org) —Not all precipitation is created equal. Using a unique uncertainty quantification (UQ) technique, scientists at Pacific Northwest National Laboratory, Scripps Institution of Oceanography, and Nanjing University calibrated the ratio between showery and stormy rain for simulations in a popular atmospheric model. Although current model results depict total precipitation fairly well, the details of precipitation type or origin does not compare well to real-life observations. The team, led by PNNL’s Dr. Yun Qian, tested the sensitivity of precipitation and atmospheric circulation to several key variables used in the model. The new model results matched observations in both cases. …read more
Source: FULL ARTICLE at Phys.org
A decade of data discloses influence of clouds on tropical energy balance
(Phys.org) —A cloud’s class and status matters to the climate. That’s what researchers at Pacific Northwest National Laboratory found when they separated tropical clouds into seven categories. Clouds with low bases are more influential than high clouds because the low-base clouds have a greater effect on the amount of solar energy that reaches the ground. They also compared the clouds’ effects on the tropical energy balance using data collected from ten years of ground-based observations at U.S. Department of Energy (DOE) sponsored locations in the tropical western Pacific region. Their findings show that cloud type is more important than previous satellite-based studies suggest. …read more
Source: FULL ARTICLE at Phys.org
A new method for measuring the viscosity of nanoparticles
For the first time, scientists measured the chemical diffusivity and viscosity of atmospheric organic particles, thanks to a new approach from scientists at Pacific Northwest National Laboratory, University of Washington, and Imre Consulting. The team doped atmospherically important organic nanoparticles, known as secondary organic aerosols (SOAs), with tracer molecules and measured their diffusion rate as they slowly worked their way out of the particles. Knowing the diffusion rate, the scientists calculated the particle’s viscosity. …read more
Source: FULL ARTICLE at Phys.org
Catalysts' outer coordination spheres take their place in the spotlight
(Phys.org) —Once dismissed as shrubbery, experimental and computational research shows the outer coordination sphere greatly influences a catalyst’s effectiveness, according to Dr. Wendy Shaw at Pacific Northwest National Laboratory in her invited review article. The outer coordination sphere is the complex structure that wraps around the catalyst’s central active site and controls the activity, selectivity and specificity of the catalyst. Shaw’s Catalysis Reviews article focuses on bottom-up design research. In this approach, aspects of the outer coordination sphere are added as needed. …read more
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Seeing the messages microbes send: Novel chemical imaging instrument shows how bacteria support nearby colonies
(Phys.org) —With a novel technique that noninvasively analyzes microbes, scientists at Pacific Northwest National Laboratory profiled, for the first time, the chemicals that a cyanobacterium makes available to others. Over 4 days, Synechococcus sp. PCC 7002 steadily secretes two molecules that could be used as resources by other bacteria that are nearby. The technique that chemically profiles the microbial communities in both space and time is Nanospray Desorption Ionization Electrospray Mass Spectrometry, or nano-DESI. This instrument was built by Dr. Julia Laskin and her team at Pacific Northwest National Laboratory. This research graced the cover of Analyst. …read more
Source: FULL ARTICLE at Phys.org
New river-routing model improves simulations of water movement within the Earth's system
A new river-routing model improves computer simulations of the magnitude and timing of water flow through the landscape and into the ocean, thanks to the work of a research team led by Dr. Ruby Leung at Pacific Northwest National Laboratory. Designed to work in tandem with land and Earth systems models, this new tool is better at simulating water flow at different scales than some widely used large-scale routing models. The model also can simulate river dynamics, including variations in depth and the velocity of river flow. …read more
Source: FULL ARTICLE at Phys.org
Reaching ambitious greenhouse gas concentration goals
Researchers at Pacific Northwest National Laboratory found that even though it is technically possible to reach ambitious goals to limit greenhouse gas concentrations by the end of the 21st century, the combined effects of limitations in technology availability and uneven global participation to curb emissions will affect costs. In addition, if the world’s largest greenhouse gas emitters do not take any action to reduce emissions by the end of the century, those ambitious goals are impossible to reach no matter how much energy technologies improve. …read more
Source: FULL ARTICLE at Phys.org
Photobioreactor enables systems biology studies of cyanobacteria
A novel photobioreactor designed and developed at Pacific Northwest National Laboratory for cultivating photosynthetic bacteria and microalgae will be featured in the journal Bioresource Technology. PNNL researchers are using the photobioreactor to identify conditions for achieving maximal growth and productivty of cyanobacteria, important components of major ecosystems and potential catalysts for sustainable biofuel and chemical production. Among its unique attributes, the bioreactor provides exquisite control over the intensity and spectrum of photosynthetically active wavelengths of light driving growth of the phototrophic cultures. …read more
Source: FULL ARTICLE at Phys.org
Dust dries clouds by gobbling up water vapor: Scientists show how different cloud seeds can influence greenhouse effect
(Phys.org)—High in the atmosphere, cold and wispy cirrus clouds are the setting for a climate competition. Researchers at Pacific Northwest National Laboratory found that dust particles in the atmosphere can grab enough water vapor available to reduce the overall number of ice crystals formed in those clouds by other particles. Though somewhat scarce, the cloud-drying dust has an impact on Earth’s incoming and outgoing energy that results in a net effect to cool the planet. …read more
Source: FULL ARTICLE at Phys.org
Ions shed water to slide into the perfect pore: Metal ions refuse to lose for large gaps, but will for a tighter fit
(Phys.org)—To slide into nano-sized openings inside minerals, certain metals shed layers of water, according to the NISE (pronounced “nice”) theory, first published in 2011 by Dr. Cristian Schulthess and his colleagues. Recently, scientists at Pacific Northwest National Laboratory worked with Schulthess and his student Dan Ferreira to test the NISE theory. Ferreira traveled to PNNL, where he was assisted by Dr. Eric Walter and Dr. James Amonette in the use of a specialized instrument at EMSL that measures key aspects of a metal’s behavior. They compared the reactions of manganese and copper ions with three different-sized pores in zeolite, a common type of mineral. Artwork from this study graced the cover of Clays and Clay Minerals. …read more
Source: FULL ARTICLE at Phys.org
Catalyst becomes more selective after oxygen atoms' departures
Using chemical imaging techniques, scientists at Pacific Northwest National Laboratory proved for the first time that titanium dioxide’s surface defects shelter chemicals from decays caused by ultra-violet light. The defects are tiny gaps created when oxygen atoms are missing from the surface of this popular catalyst. Conventional wisdom says the vacancies are more active than the surface. The team showed the opposite is true for photooxidation. The carbon-based carboxylic group, trimethyl acetate (TMA), remains intact if bound in the vacancies while it readily decomposes at regular, or non-vacancy, sites on the surface. …read more
Source: FULL ARTICLE at Phys.org
Lanthanum chromium oxide's energetic dance with light
Scientists at Pacific Northwest National Laboratory, University College London, and Florida International University have determined how a particular oxide material, lanthanum chromium oxide (LCO), interacts with visible and ultraviolet light. …read more
Source: FULL ARTICLE at Phys.org
Influence of cosmic rays on cloud droplet formation explored in a global climate model
A research team from the State University of New York-Albany and Pacific Northwest National Laboratory used a global atmospheric model to estimate that charged ions produced by cosmic rays in the atmosphere increase new atmospheric particles formed by a factor of ten when compared with particles formed by a corresponding neutral, non-charged, mechanism. Though cosmic rays ionization is important in forming aerosol particles and altering the make-up of clouds, the team determined that the changes during the solar cycle are insufficient to produce a measurable change in the Earth’s energy balance. …read more
Source: FULL ARTICLE at Phys.org
Chemical imaging microscope shows corrugated gamma-alumina surface
(Phys.org)—Neither smooth nor disordered, gamma-alumina nanoparticles are corrugated with tiny pores inside, according to scientists at Pacific Northwest National Laboratory. Using a powerful transmission electron microscope, the team obtained ultrahigh-resolution images and chemical data about the particle’s surface. They found that the particles were covered with ridges made from a more open, yet symmetrical, arrangement of atoms. The open arrangement on the surfaces, notated as (110), covers 70% of the nanoparticle.
Source: FULL ARTICLE at Phys.org
The biology of plague: Systems approach used to investigate strains of Yersinia
(Phys.org)—When is the plague not the plague? When it’s a different strain of the same bacteria. In two strains of the bacteria genus Yersinia —a highly lethal pathogen and its less-virulent form—scientists performed multi-omic analyses to gain insights how they differ. They found that how the genes in both are expressed contribute to the striking difference in the diseases caused by these pathogens. The research team included scientists from Pacific Northwest National Laboratory, the J. Craig Venter Institute, and the University of Texas Medical Branch.
Source: FULL ARTICLE at Phys.org
Cotton-ball clouds contained: New modeling method captures clouds' shading effects
(Phys.org)—Small clouds equal big impact. Researchers at Pacific Northwest National Laboratory designed an update to a frequently used computer model that represents the impact of small, puffy, fair-weather clouds on the amount of sunshine reaching Earth’s surface. The new method includes variations in temperature and humidity near the surface and their role in forming these small clouds. Their method offers improved climate forecasts and better cloud prediction, including the amount of sunshine the clouds reflect.
Source: FULL ARTICLE at Phys.org













