Tag Archives: EMSL

Theory models, EMSL capabilities illuminate how particles grow in the atmosphere

Determining the chemical mechanisms that govern new particle formation, or NPF, in the atmosphere is not something that can be pulled out of thin air. In the atmosphere, nucleating clusters are presumed to be composed of a few common species: sulfuric acid (the key chemical component), ammonia, amines (ammonia derivatives), and water—all of which have different effects on nucleation and particle growth. Moreover, these same clusters may significantly impact cloud condensation nuclei, the particles that spawn cloud formation, and, in turn, affect global climate. Scientists used EMSL‘s Fourier transform ion cyclotron resonance mass spectrometer equipped with surface-induced dissociation (SID) to examine and model fragmentation kinetics and energetics of small clusters that may serve as precursors to NPF. …read more

Source: FULL ARTICLE at Phys.org

Nanoclusters in steel add strength, stability under irradiated conditions

Safely containing and retarding the mobility of reactor fuels are longstanding U.S. Department of Energy and Department of Defense concerns, making the radiation stability of the materials used for structural components and fuel cladding critically important. In this study, scientists used various analysis tools, including EMSL‘s atom probe tomography (APT), focused ion beam, and accelerator capabilities, to examine complex oxide nanoclusters within oxide dispersion strengthened, or ODS, steels to determine their potential resistance and stability under a range of irradiation conditions. The complex nanoclusters in ODS steels increase the metal’s high-temperature strength, making ODS steel viable for use in nuclear structure or cladding applications. …read more
Source: FULL ARTICLE at Phys.org

Ions shed water to slide into the perfect pore: Metal ions refuse to lose for large gaps, but will for a tighter fit

(Phys.org)—To slide into nano-sized openings inside minerals, certain metals shed layers of water, according to the NISE (pronounced “nice”) theory, first published in 2011 by Dr. Cristian Schulthess and his colleagues. Recently, scientists at Pacific Northwest National Laboratory worked with Schulthess and his student Dan Ferreira to test the NISE theory. Ferreira traveled to PNNL, where he was assisted by Dr. Eric Walter and Dr. James Amonette in the use of a specialized instrument at EMSL that measures key aspects of a metal’s behavior. They compared the reactions of manganese and copper ions with three different-sized pores in zeolite, a common type of mineral. Artwork from this study graced the cover of Clays and Clay Minerals. …read more
Source: FULL ARTICLE at Phys.org